Cycloaddition of allyl radical to methylacetylene.
نویسندگان
چکیده
منابع مشابه
The dynamics of allyl radical dissociation.
Dissociation of the allyl radical, CH(2)CHCH(2), and its deuterated isotopolog, CH(2)CDCH(2), have been investigated using trajectory calculations on an ab initio ground-state potential energy surface calculated for 97,418 geometries at the coupled cluster single and double and perturbative treatment of triple excitations, with the augmented correlation consistent triple-ζ basis set level (CCSD...
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The A [(2)B1] <--X [(2)A2] band system between 380 and 420 nm was observed in a supersonic jet expansion. The allyl radical was found to dissociate following electronic excitation, releasing a hydrogen atom. Monitoring the appearance of the hydrogen atom photoproduct as a function of the excitation laser wavelength, similar spectral features are observed as in earlier absorption experiments. Ti...
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ژورنال
عنوان ژورنال: Journal of The Japan Petroleum Institute
سال: 1981
ISSN: 0582-4664
DOI: 10.1627/jpi1958.24.122